Electrochemical driven water oxidation by molecular catalysts in situ polymerized on the surface of graphite carbon electrode.
نویسندگان
چکیده
A simple strategy to immobilize highly efficient ruthenium based molecular water-oxidation catalysts on the basal-plane pyrolytic graphite electrode (BPG) by polymerization has been demonstrated. The electrode 1@BPG has obtained a high initial turnover frequency (TOF) of 10.47 s(-1) at ∼700 mV overpotential, and a high turnover number (TON) up to 31600 in 1 h electrolysis.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 37 شماره
صفحات -
تاریخ انتشار 2015